Its boiling point may be low, but it's far higher than it should be for such a small molecule. 0 0. This is because phosphorus is bigger have bigger size as compare to nitrogen thus have weak bonding with hydrogen. it can form h-bonds between its molecules. In case of NH 3 and PH 3, ammonia has higher boiling point than phosphine because of hydrogen bonding. The oxygen in water, however, has two free electron pairs so it can form two hydrogen bonds. Why? This is due to the fact of intermolecular forces,IMFs. NH three is the president of hydrogen bonding, so essentially and aged three has a higher boiling point because it has stronger inter molecular forces. Beside above, why does HBr have a high boiling point than HCl? the boiling point of ammonia is -33 degree Celsius. Ammonia contains a strongly electronegative element (N) bound to hydrogen, allowing it to form strong hydrogen bonds. In the case of ammonia, the amount of hydrogen bonding is limited by the fact that each nitrogen only has one lone pair. In PH 3 and other hydrides, the intermolecular forces are van der Waals forces. So the Ph three exhibit stronger London Dispersion forces, however unique to ammonia. Relevance. This is why the boiling point of water is higher than that of ammonia or hydrogen fluoride. {"items":["5fa8a86123d2090017630230"],"styles":{"galleryType":"Columns","groupSize":1,"showArrows":true,"cubeImages":true,"cubeType":"max","cubeRatio":1.7777777777777777,"isVertical":true,"gallerySize":30,"collageAmount":0,"collageDensity":0,"groupTypes":"1","oneRow":false,"imageMargin":12,"galleryMargin":0,"scatter":0,"rotatingScatter":"","chooseBestGroup":true,"smartCrop":false,"hasThumbnails":false,"enableScroll":true,"isGrid":true,"isSlider":false,"isColumns":false,"isSlideshow":false,"cropOnlyFill":false,"fixedColumns":0,"enableInfiniteScroll":true,"isRTL":false,"minItemSize":50,"rotatingGroupTypes":"","rotatingCropRatios":"","columnWidths":"","gallerySliderImageRatio":1.7777777777777777,"numberOfImagesPerRow":3,"numberOfImagesPerCol":1,"groupsPerStrip":0,"borderRadius":0,"boxShadow":0,"gridStyle":0,"mobilePanorama":false,"placeGroupsLtr":true,"viewMode":"preview","thumbnailSpacings":4,"galleryThumbnailsAlignment":"bottom","isMasonry":false,"isAutoSlideshow":false,"slideshowLoop":false,"autoSlideshowInterval":4,"bottomInfoHeight":0,"titlePlacement":["SHOW_ON_THE_LEFT","SHOW_BELOW"],"galleryTextAlign":"center","scrollSnap":false,"itemClick":"nothing","fullscreen":true,"videoPlay":"hover","scrollAnimation":"NO_EFFECT","slideAnimation":"SCROLL","scrollDirection":0,"scrollDuration":400,"overlayAnimation":"FADE_IN","arrowsPosition":0,"arrowsSize":23,"watermarkOpacity":40,"watermarkSize":40,"useWatermark":true,"watermarkDock":{"top":"auto","left":"auto","right":0,"bottom":0,"transform":"translate3d(0,0,0)"},"loadMoreAmount":"all","defaultShowInfoExpand":1,"allowLinkExpand":true,"expandInfoPosition":0,"allowFullscreenExpand":true,"fullscreenLoop":false,"galleryAlignExpand":"left","addToCartBorderWidth":1,"addToCartButtonText":"","slideshowInfoSize":200,"playButtonForAutoSlideShow":false,"allowSlideshowCounter":false,"hoveringBehaviour":"NEVER_SHOW","thumbnailSize":120,"magicLayoutSeed":1,"imageHoverAnimation":"NO_EFFECT","imagePlacementAnimation":"NO_EFFECT","calculateTextBoxWidthMode":"PERCENT","textBoxHeight":100,"textBoxWidth":200,"textBoxWidthPercent":75,"textImageSpace":10,"textBoxBorderRadius":0,"textBoxBorderWidth":0,"loadMoreButtonText":"","loadMoreButtonBorderWidth":1,"loadMoreButtonBorderRadius":0,"imageInfoType":"ATTACHED_BACKGROUND","itemBorderWidth":0,"itemBorderRadius":0,"itemEnableShadow":false,"itemShadowBlur":20,"itemShadowDirection":135,"itemShadowSize":10,"imageLoadingMode":"BLUR","expandAnimation":"NO_EFFECT","imageQuality":90,"usmToggle":false,"usm_a":0,"usm_r":0,"usm_t":0,"videoSound":false,"videoSpeed":"1","videoLoop":true,"jsonStyleParams":"","gallerySizeType":"px","gallerySizePx":292,"allowTitle":true,"allowContextMenu":true,"textsHorizontalPadding":-30,"itemBorderColor":{"themeName":"color_12","value":"rgba(69,64,64,0)"},"showVideoPlayButton":true,"galleryLayout":2,"calculateTextBoxHeightMode":"MANUAL","targetItemSize":292,"selectedLayout":"2|bottom|1|max|true|0|true","layoutsVersion":2,"selectedLayoutV2":2,"isSlideshowFont":true,"externalInfoHeight":100,"externalInfoWidth":0.75},"container":{"width":220,"galleryWidth":232,"galleryHeight":0,"scrollBase":0,"height":null}}, How to Draw Lewis Dot Structures? In cooling the mixture loses heat. this strong h-bonds require more energy to overcome. 3. Since ammonia features hydrogen bonding (owing to the presence of covalent bonds between hydrogen and nitrogen, which is relatively more electronegative and has a lone pair), it has a higher boiling point than phosphine. However, the boiling point of methylamine is -6.3°C, whereas ethane's boiling point is much lower at -88.6°C. However, we can compare ammonia with other molecules and explain why the boiling point is such relative to the boiling point of these substances.